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Model 204 – Sample Transfer
Stripper (STS) Patented
Measure Volatile Hydrocarbons in Water
VOC’s in Water Model 204-V or Oil in Water Model 204-O
Click
here for diagram or
here for photograph.
PRINCIPLES OF OPERATION:
The ASI / KECO Model 204 incorporates
basic principles covered by patent 5,398,559 and patents pending.
A liquid or gas
sample is allowed to continuously flow past one side of a
non-selective permeable membrane while a carrier gas,
hydrocarbon-free air, continuously flows past the other side of the
membrane. Sample components permeate the membrane and are swept away
to make a mixture of gases suitable for analysis. An exclusive &
patented liquid Validation System is available as an option.
Texas Commission on
Environmental Quality (TCEQ) has designated the Model 204 as “Best
Available Control Technology” and “Equivalency” for
continuous monitoring of cooling tower waste water applications. In
addition, Shell Global has awarded us Preferred Vendor.
FEATURES:
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Save |
On lab
analysis costs, unattended online analysis |
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Safe |
Purge
option for explosion proof rating |
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Economical |
Payout
within days by preventing lost product. Losses of 12,000
pounds per day are caused by leaks |
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Low maintenance |
Less
than 5% of the service time for sparger or TOC analyzers |
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Built-in Liquid calibrator |
Liquid
Permeation tube or Microinject™ type, manual or timer
type |
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Accurate |
Grab
samples for the lab deteriorate with time, VOC's escape
during sampling |
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Accessories |
Motorized spin clean filter and carrier purifier. A
probe can be inserted in a line carrying plastic pellets |
TYPICAL APPLICATIONS
Heat Exchangers
Monitoring for hydrocarbon in cooling water or condensate allows
the earliest warning of developing leaks. Maintenance can be
scheduled in advance of costly equipment failure when leakage rate
data is used for forecasting purposes. Boiler feed water monitoring
for hydrocarbon, from heat exchangers can prevent power generation
equipment damage. A validation permeation tube is optional.
Cooling Towers and Holding
Ponds
Equipment leaks, spills, and drainage run-offs can cause
build-up of hydrocarbon in the water. The Model 204 can give a
continuous online indication of the volatile organic carbon (VOC)
contained in these waters. Hand truck mounting and battery powered
options available as well as laboratory models. Steam can be
analyzed using a condensing coil.
Waste Water
Where the dissolved hydrocarbon or oil content could be PPBw,
PPMw, or at saturation levels, Model 204 can be easily configured to
provide continuous measurement online.
Process Stream Analysis and
Laboratory Analyzers
Model 204 is compatible with GC, IR, UV, Mass Spec, Moisture and
Tape type analyzers for measuring the components of interest in gas
or liquid hydrocarbon sample streams. Applications include, but are
not limited to:
* Measurement of H2S in
Fuel Gas, Liquid Aromatics, Kerosene, Gasoline, Beverages, Amine
Treated Gas, Sour Gas and Water
* Measurement of Volatile H/C's from Hydrocarbon Gas Streams,
Hydrocarbon Liquid Streams, Aromatics, Alcohols, oils, and Paraffins
in Water Streams. For many of these applications, a readout able to
identify hydrocarbons is required such as a GC.
HYDROCARBONS IN COOLING TOWER
WATER
Leaks of hydrocarbons from heat
exchangers can emit large quantities of Volatile Organic Carbons
(VOC). This can be a hazard from a flammability standpoint as well
as cause emissions into the atmosphere. 99.9 to 100% of VOC are
stripped to the atmosphere in cooling towers and have been found to
be 12,576 pounds per day from a single exchanger. On-line continuous
monitoring can pay for an analyzer in a short time by warning of
corrosion leaks. Savings in lost product and laboratory time can be
substantial.
Hydrocarbon in Cooling Water
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Chemical |
Saturation
in Water
PPMw |
Headspace
Concen.
% |
Lower
Explosive
Limit in % |
PPMw in
Water for
Lower
Explosion
Limit |
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Benzene |
700 |
11.1 |
1.35 |
85 |
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Propylene |
762 |
100 |
2.00 |
15 |
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Hexane |
140 |
19.7 |
1.25 |
9 |
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Propane |
120 |
100 |
2.2 |
2.6 |
Fortunately, airflow through a
cooling tower dilutes the hydrocarbon, allowing higher
concentrations than shown on the right column before the cooling
tower catches fire.
A typical cooling tower with 10 PPM
by weight hydrocarbon content will emit 15,000 lbs./day lost
product.
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ETHYLENE & PROPYLENE
PLANTS
ASI / KECO INSTRUMENT APPLICATIONS USING
SAMPLE TRANSFER STRIPPER™ |
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TYPICAL INSTALLATIONS MODEL 204,
APPROVED BY TNRCC FOR REPORTING. |
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1. MEASURE HYDROCARBONS IN
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COOLING WATER.
RANGING:
0 to 10 PPB or PPM to saturation
MEASURES: Volatile Organic Carbon (VOC)
in water. Any hydrocarbon having a hydrogen carbon bond
to molecular weights of several hundred.
READ-OUT:
GC if there is need to identify hydrocarbon.
Solid state sensor to measure total VOC or when
hydrocarbon is known. Mass Spectrometer.
MEASURING POINT:
Cooling tower, a group of heat exchangers,
steam condensate. Can be used to calculate emission
rates or prevent loss of product.
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2. CLEAN-UP OF CONTAMINATED
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WATER, MEASURE INPUT AND
OUTPUT VOC
STEAM STRIPPER: Measure VOC at
input and output control steam required & save fuel
costs or to regulate maximum through output
CARBON BED
STRIPPER: Same as above
BIOLOGICAL
PROCESS: Regulate additives, oxygen required,
output rate.
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3. PELETIZED PLASTIC PRODUCTS: |
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Use Model 204 with membrane probe to measure
hydrocarbons and/or oxygen in process pipes, for
nitrogen or steam drive. Use to report emission rates or
warn of hazardous concentrations. Sample can be brought
to the analyzer rather than use a probe. A 2" gate or
ball valve can be used to insert and withdraw a probe.
Calibration
methods: Permeation tubes can be used to
generate PPM or PPB samples to validate analyzer
response. A liquid or gas trace can be fed into a liquid
or gas stream. Alternatively, ASI / KECO can supply its
proprietary Microinjector™ method to directly inject
trace liquids or water saturated with propylene, for
example, to make PPM or PPB calibration standards.
Low maintenance:
Membrane Sample Transfer™ for sampling
radically reduces maintenance for GC,
MS, IR, UV and solid state analyzers. The clean, dry
sample can pay for the sample preparation system by
lowering maintenance time and cost. |
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Home |
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Permeation Trans. Monitor |
Volatile Hydro. Anal. |
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Membrane Sample Trans. |
Membrane Probe Trans. |
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Permeation Tube Calibrator |
Permeation Tubes |
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Microliter Fluid Calibrator |
Sensor Calibration |
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Membrane Transfer Technology |
TNRCC Letter |
Phone:
281-516-3950 Fax: 281-351-8925
Analytical Systems International / Keco
™ Trademark Analytical Systems International Keco R.&D., Inc.
Patent # 5,156,334 and Patent Pending
© 1994-2004 Analytical Systems International Keco R.& D., Inc |